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Mechanistic Study of Ru-NHC-Catalyzed Hydrodefluorination of Fluoropyridines: The Influence of the NHC on the Regioselectivity of C–F Activation and Chemoselectivity of C–F versus C–H Bond Cleavage

机译：Ru-NHC催化的氟吡啶氢加氟反应机理研究：NHC对CF活化的区域选择性和CF与CH键断裂的化学选择性的影响

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Mckay, David; Riddlestone, Ian M.; Macgregor, Stuart A.; Mahon, Mary F.; Whittlesey, Michael K.;
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年度 2015
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1. Mechanistic Study of Ru-NHC-Catalyzed Hydrodefluorination of Fluoropyridines: The Influence of the NHC on the Regioselectivity of C-F Activation and Chemoselectivity of C-F versus C-H Bond Cleavage [J] . McKay David, Riddlestone Ian M., Macgregor Stuart A., ACS catalysis . 2015,第2期

机译：Ru-NHC催化的氟吡啶氢加氟作用机理的研究：NHC对C-F活化的区域选择性和C-F与C-H键断裂的化学选择性的影响
2. Regioselective C-F Bond Activation/C-C Bond Formation between Fluoropyridines and Cyclopropyl Groups at Zirconium [J] . Romero Nuria, Dufrois Quentin, Crespo Natalie, Organometallics . 2020,第12期

机译：锆之间的氟吡啶和环丙基之间的区域选择性C-F键活化/ C-C键形成
3. Computational study of the hydrodefluorination of fluoroarenes at [Ru(NHC)(PR_3)_2(CO)(H)_2]: Predicted scope and regioselectivities [J] . MacGregor S.A., McKay D., Panetier J.A., Dalton transactions: An international journal of inorganic chemistry . 2013,第20期

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4. Mechanistic Insights on C-C Bond Cleavage, C-O Bond Cleavage, and Hydrogen Insertion in Light Carboxylic Acids Catalyzed by Dispersed Ruthenium Clusters in Aqueous Medium [C] . Junnan Shangguan, Ya-Huei (Cathy) Chin AIChE Annual Meeting . 2015

机译：在水性介质中分散的钌簇催化的光羧酸中C-C键切割，C-O键切割和氢气插入的机械洞察
5. Palladium-mediated carbon-carbon bond formation: Methodology and mechanism. Part I: Palladium-catalyzed alpha-arylation of aryl nitromethanes, phosphonoacetates, and phosphine oxides. Part II: Mechanistic study of the palladium-mediated chemoselective activation of C(sp3)-H bonds. [D] . VanGelder, Kelsey Faith. 2016

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6. The key role of R–NHC coupling (R = C H heteroatom) and M–NHC bond cleavage in the evolution of M/NHC complexes and formation of catalytically active species [O] . Victor M. Chernyshev, Ekaterina A. Denisova, Dmitry B. Eremin, 2020

机译：R-NHC偶联（R = CH杂原子）和M-NHC键在M / NHC复合物的演变中的关键作用和M-NHC键切割和催化活性物种的形成
7. Mechanistic Study of Ru-NHC-Catalyzed Hydrodefluorination of Fluoropyridines: The Influence of the NHC on the Regioselectivity of C–F Activation and Chemoselectivity of C–F versus C–H Bond Cleavage [O] . Mckay David, Riddlestone Ian M., Macgregor Stuart A., 2015

机译：Ru-NHC催化的氟吡啶氢加氟反应机理研究：NHC对CF活化的区域选择性和CF与CH键断裂的化学选择性的影响

Mechanistic Study of Ru-NHC-Catalyzed Hydrodefluorination of Fluoropyridines: The Influence of the NHC on the Regioselectivity of C–F Activation and Chemoselectivity of C–F versus C–H Bond Cleavage

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